Sobrinho Lab

Imperial College

- · United Kingdom

ERC-funded
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ERC Consolidator Grant · 2016

The Lignin-First Approach for the Full Valorisation of Lignocellulosic Biomass

Early-stage Catalytic Conversion of Lignin (ECCL), or the ‘Lignin-First’ approach, constitutes an emerging multidisciplinary research field targeting the valorisation of lignin. ECCL involves the concurrent extraction and catalytic conversion of the lignin fragments released from plant biomass in a one-pot process. In this manner, ECCL benefits from the intrinsically high reactivity of the lignin oligomers, leading to further depolymerisation (via hydrogenolysis of ether linkages) and, most importantly, to the passivation of the intermediates (via hydrodeoxygenation of aldehyde and ketone groups), thus protecting the lignin fragments from recondensation. In short, this novel approach…

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