Berionni Lab

University of Namur

Région wallonne (BE3) · Belgium

ERC-funded
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ERC Consolidator Grant · 2021

Reprogramming the reactivity of main-group compounds for capturing and activating methane and dinitrogen

The activation of chemical bonds is fundamental to every chemical transformation. While reactions mediated by transition-metal catalysts are known for more than a century, the last decade witnessed spectacular developments in the emerging area of catalysis mediated by non-metallic species. Among these new chemical entities made from earth-abundant and inexpensive main-group elements, Lewis acid-base pairs and bifunctional element/ligand systems mimicking the behavior of transition-metals rapidly revolutionized the activation modes of chemical bonds. In the project B-yond, I will establish new molecular engineering strategies and develop unprecedented main-group catalysts embedded in…

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