Greenfield Lab

University of St. Andrews

- · United Kingdom

ERC-funded
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ERC Starting Grant · 2025

Helical Out-of-Equilibrium Systems: Exploring Light-Induced Structural Distortions

Helical architectures are prevalent in natural and artificial settings due to their mechanical robustness, chiroptical properties, and ability to assemble compactly through intra- and intermolecular interactions. We propose that reversible distortions to these structures can unlock new behaviors. Inspired by recent advancements in supramolecular chemistry and light-responsive molecules, we aim to couple light-responsive units (LRUs) to helical structures to drive them out-of-equilibrium (OOE), thereby modulating their functionality and achieving photoactuation. Adopting organic and metal-organic spring-like model systems, we aim to achieve compression, extension, and complete unwinding of…

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